Regularized resolvent transform for direct calculation of 45 degrees projections of 2D J spectra.

نویسندگان

  • Geoffrey S Armstrong
  • Jianhan Chen
  • Kristin E Cano
  • A J Shaka
  • Vladimir A Mandelshtam
چکیده

The regularized resolvent transform (RRT) has been applied in a novel way to J-resolved spectra. This involves the direct calculation of the 45 degrees projection without constructing the 2D spectrum. The results show a significant resolution enhancement over that obtained by the 45 degrees projection of a 2D Fourier spectrum, even for much larger signals. In particular, RRT is able to resolve peaks that belong to different overlapping multiplets in a very crowded spectral region, where the conventional technique fails for any signal size. The resolving power of this method along with the significantly shorter signals required, make this method a powerful tool in spectral assignment.

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عنوان ژورنال:
  • Journal of magnetic resonance

دوره 164 1  شماره 

صفحات  -

تاریخ انتشار 2003